Combine espresso, vodka, coffee liqueur, and simple syrup in a cocktail shaker.
The ratio of espresso to spirits determines whether this is a coffee drink with alcohol or an alcohol drink with coffee. At 30ml espresso to 60ml combined spirits, coffee dominates the flavour. Mr Black (40% ABV, very coffee-forward) produces a drier, more bitter, coffee-centric result. Kahlúa (20% ABV, sweeter, with vanilla notes) produces a more balanced, dessert-leaning result. The simple syrup may be omitted entirely when using Kahlúa.